WebSep 14, 2024 · Phosphine is a toxic, malodorous gas that is extremely poisonous and has been used in chemical weapons. The molecule is composed of one phosphorus atom and three hydrogen atoms, and is shaped... Phosphine (IUPAC name: phosphane) is a colorless, flammable, highly toxic compound with the chemical formula PH3, classed as a pnictogen hydride. Pure phosphine is odorless, but technical grade samples have a highly unpleasant odor like rotting fish, due to the presence of substituted phosphine and … See more Philippe Gengembre (1764–1838), a student of Lavoisier, first obtained phosphine in 1783 by heating white phosphorus in an aqueous solution of potash (potassium carbonate). Perhaps because of … See more PH3 is a trigonal pyramidal molecule with C3v molecular symmetry. The length of the P−H bond is 1.42 Å, the H−P−H bond angles are … See more Organophosphorus chemistry Phosphine is a precursor to many organophosphorus compounds. It reacts with formaldehyde in the presence of hydrogen chloride to give tetrakis(hydroxymethyl)phosphonium chloride, … See more • Fluck, E. (1973). "The Chemistry of Phosphine". Topics in Current Chemistry. Fortschritte der Chemischen Forschung. 35: 1–64. doi:10.1007/BFb0051358. ISBN 3-540-06080-4 See more Phosphine may be prepared in a variety of ways. Industrially it can be made by the reaction of white phosphorus with sodium or potassium hydroxide, … See more Deaths have resulted from accidental exposure to fumigation materials containing aluminium phosphide or phosphine. It can be absorbed either by inhalation See more • Diphosphane, H2P−PH2, simplified to P2H4 • Diphosphene, HP=PH See more
Communication: Tunnelling splitting in the phosphine molecule
WebSep 14, 2024 · Phosphine is a compound made from phosphorus and hydrogen, and on Earth its only natural source is tiny microbes that live in oxygen-free environments. It’s too early to say whether phosphine... WebFeb 6, 2024 · We conducted detailed investigations of the effect of aryl azide and phosphine structure on both the mechanism and kinetics of these reaction-induced eliminations and identified phosphine/azide... eagle search tntech
EXPERT REACTION: Phosphine gas discovery has us wondering
WebOct 22, 2024 · Phosphine, the simplest phosphorus hydride, is a colorless and extremely toxic gas. Some people think it smells like rotting fish; it reminds others of the odor of … WebNov 3, 2024 · phosphine: [noun] any of various derivatives of phosphine analogous to amines but weaker as bases. csm chapter 21